When a powder diffraction pattern is looked at, the peak linewidths may vary as a function of scattering angle 2\theta in a non-uniform fashion. This could arise from a given internal strain distribution, from anisotropic sample size broadening, or from a given defect pattern (for example, stacking faults). Here, I will concentrate on the broadening due to strain. The simplest method for dealing with this is to consider isotropic or uniform strain, in which case the full-width half-maxima (FWHMs) of the Bragg peaks will be proportional to tan \theta. If the strain is not uniform, the problem is a bit harder. Here, I will follow P. W. Stephens’ approach, outlined in an article in the Journal of Applied Crystallography, published in 1999.
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